Search results for "Hydrogen storage"
showing 10 items of 56 documents
Structural characterization and electrochemical hydrogen storage properties of Ti2LxZrxNi (x [ 0, 0.1, 0.2) alloys prepared by mechanical alloying
2013
International audience; Nominal Ti2Ni was synthesized under argon atmosphere at room temperature using a planetary high-energy ball mill. The effect of milling time and Zr substitution for Ti on the microstructure was characterized by XRD, SEM and TEM, and the discharge capacities of Ti2xZrxNi (x 1/4 0, 0.1, 0.2) were examined by electrochemical measurements at galvanostatic conditions. XRD analysis shows that amorphous phase of Ti2Ni can be elaborated by 60 h of milling, whereas Zr substitution hinders amorphization process of the system. The products of ball milling nominal Ti2xZrxNi (x 1/4 0.1, 0.2) were austenitic (Ti, Zr)Ni and partly TiO, despite the fact that the operation was carrie…
Coordination nano-space as stage of hydrogen ortho–para conversion
2015
The ability to design and control properties of nano-sized space in porous coordination polymers (PCPs) would provide us with an ideal stage for fascinating physical and chemical phenomena. We found an interconversion of nuclear-spin isomers for hydrogen molecule H 2 adsorbed in a Hofmann-type PCP, {Fe(pz)[Pd(CN) 4 ]} (pz=pyrazine), by the temperature dependence of Raman spectra. The ortho (o)–para (p) conversion process of H 2 is forbidden for an isolated molecule. The charge density study using synchrotron radiation X-ray diffraction reveals the electric field generated in coordination nano-space. The present results corroborate similar findings observed on different systems and confirm …
Optimizing Renewable Power Management in Transmission Congestion. An Energy Hub Model Using Hydrogen Storage
2021
Energy production from distributed renewable power plants underwent a takeoff in last years as never before. Nevertheless, the installation of technologies based on variable energy resources and their connection on transmission power lines might cause congestions due to the transmission capacity limits. This paper describes the modelization of a HV transmission line with local renewable production and its optimal management through an Energy Hub model. Aim of the study is to identify the optimal size of the power storage, based on an electoryzer, a hydrogen storage and a fuel cell, in order to minimize the congestion risks and to maximize the exploitation of renewable energy production.
Eulerian two-fluid model of alkaline water electrolysis for hydrogen production
2020
Hydrogen storage is a promising technology for storage of renewable energy resources. Despite its high energy density potential, the development of hydrogen storage has been impeded, mainly due to its significant cost. Although its cost is governed mainly by electrical energy expense, especially for hydrogen produced with alkaline water electrolysis, it is also driven by the value of the cell tension. The most common means of electrolyzer improvement is the use of an electrocatalyst, which reduces the energy required for electrochemical reaction to take place. Another efficient means of electrolyzer improvement is to use the Computational Fluid Dynamics (CFD)-assisted design that allows the…
An experimental investigation on the poor hydrogen sorption properties of nano-structured LaNi5 prepared by ball-milling
2011
Abstract Nano-structured LaNi5 hydrogen storage materials prepared by ball-milling is analysed using differential scanning calorimetry (DSC) and x-ray photoelectron spectroscopy (XPS). DSC results indicate a partial elimination of defects at 500 °C in a more efficient way for the short-time ball-milled powders compared to the long-time ball-milled ones. XPS results show almost no change in the core-level electronic structure for La and Ni of LaNi5 in the bulk and the nano-structured forms, but gives an indication that the self-restoring mechanism of the active surface observed in the bulk sample (Siegmann et al. Phys. Rev. Lett. 40, 972) may not be occurring in the nano-powders. Results fro…
Perspective on hydrogen energy carrier and its automotive applications
2014
The paper outlines the concept of energy carrier with a particular reference to hydrogen, in view of a more disseminated employment in the field of automotive applications. In particular hydrogen production is analyzed considering the actual state of the art and recent technologies applied in production from the primary sources (fossil fuels, renewable energies, and water electrolysis). Then the problem of hydrogen storage is considered both from technical and economical point of views. In particular, differences between physical and chemical storage are here considered with a particular glance to the most innovative technologies including carbon nanostructures. A review on the main problem…
Experimental characterization of PEM fuel cells by micro-models for the prediction of on-site performance
2009
This paper presents the results of an experimental analysis performed on a miniaturized, 6 We Proton Exchange Membrane Fuel Cell (PEMFC) system, integrated with on-site hydrogen production by electrolysis; in particular, the effects of environmental parameters such as the external temperature and the humidity on the performance of fuel cells are investigated. PEMFC systems are zero-emissions power technologies when they are fed with pure hydrogen (at concentration higher than 97%); also, being the only results of system operation the produced electricity and some pure water, when produced by renewable sources hydrogen can be considered an attractive alternative to fossil fuels and may concu…
An inertial system for the production of electricity and hydrogen from sea wave energy
2015
This paper aims at describing a small scale prototype of a complete wave energy converter system for hydrogen production promoting the opportunity of installation in Sicily, in the Mediterranean Sea. The opportunity to produce hydrogen from sea-water identifies ocean wave energy as the most promising solution for electricity generation including hydrogen production and storage. Even if hydrogen is considered one of the most promising secondary sources, criticism arises from both the academic and the industrial world mainly because hydrogen production requires electricity consumption. Furthermore, safety problems concerning hydrogen storage and transport are actually the main hindrance to fu…
Technical, Environmental and Economical Aspects of Hybrid Systems Including Renewables and Fuel Cells
2006
In this paper, some configurations including renewables and fuel cells are studied. Technical, environmental and economical aspects are treated in the frame of the EU regulations concerning the ‘emission trading’ issue and the way in which Italy has implemented the relevant EU directive. The study has been carried out considering some architectures including renewables such as photovoltaic and wind with a back up system to increase continuity of supply based on the application of fuel cells and of a hydrogen storage system. Performing several runs with different values of the cost of energy (COE) bought from the network and produced with traditional fuel, it has been observed that, for some…